Jessica Biel stunned at the 2017 Emmy Awards in L.A. on Sunday, September 17, without her usual award show date, husband Justin Timberlake, by her side — and it turns out that the actress, 35, was riding solo for a very good reason.

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Timberlake, 40, touched down in Rio de Janeiro, Brazil, to perform at Rock in Rio’s show the same night. The singer headlined the event, which also featured performances from Alicia Keys, Walk the Moon and Frejat. Attendees at the annual concert series — which fundraises for social, environmental and cultural causes — also saw Maroon 5, Shawn Mendes, Fergie and more perform on previous nights.

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